ON THE PREPARATION OF 1H-PERFLUOROALKANES AND A MECHANISM FOR THE REDUCTION OF PERFLUOROALKYL IODIDES

被引：12

作者：

HOWELL, JL

MUZZI, BJ

RIDER, NL

ALY, EM

ABOUELMAGD, MK

机构：

[1] E.I. du Pont de Nemours, Co., Inc., Jackson Laboratory, Deepwater, NJ 08023, Chambers Works

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 01期

关键词：

1H-PERFLUOROALKANES; METHYL HYPOIODIDE; MECHANISM; REDUCTION; MASS SPECTROMETRY;

D O I：

10.1016/0022-1139(94)03176-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1H-Perfluoroalkanes are prepared by sodium methoxide reduction of 1-iodoperfluoroalkanes. The experimental evidence indicates that the reaction proceeds either through a radical or a thermal mechanism. We have found that a high yield of 1H-perfluoroalkanes at complete conversion can be accomplished at atmospheric pressure using this technology.

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页码：61 / 68

页数：8

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