RUTHENIUM INDUCED DEGRADATION OF TETRAMETHYLTHIOUREA TO CARBYNE AND DICARBENE LIGANDS - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE CLUSTERS RU4(CO)10((MU-2-CNME2(MU-3-S)[MU-3-SRU(CO)3(ETA-2-CH2NMECNME2)], RU5(CO)11(MU-2-CNME2)2(MU-4-S)2 AND RU4(MU-2-CO)3(CO)6(MU-4-S)2(ETA-2-ME2NCNMECH2CNME2)

被引：20

作者：

BODENSIECK, U ^{[1
]}

STOECKLIEVANS, H ^{[1
]}

RHEINWALD, G ^{[1
]}

SUSSFINK, G ^{[1
]}

机构：

[1] UNIV NEUCHATEL,INST CHIM,AVE BELLEVAUX 51,CH-2000 NEUCHATEL,SWITZERLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 433卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)80139-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal reaction of Ru3(CO)12 with SC(NMe)2 in THF at 140-degrees-C yields, apart from (mu-2-H)Ru3(CO)9[mu-3-SRu(CO)3(eta-2-CH2NMeCNMe2)] (1) (cf. J. Organomet. Chem., 433 (1992) 149) the carbyne- and dicarbene-containing clusters RU4(CO)10(mu-2-CNMe2)-(mu-3-S)[mu-3-SRu(CO)3(eta-2-CH2NMeCNMe2)] (2), Ru5(CO)11(mu-2-CNMe2)2(mu-4-S)2 (3) and Ru4(mu-2-CO)3(CO)6(mu-4-S)2(eta-2-Me2NCNMeCH2CNMe2) (4). The pentanuclear cluster 3 can also be obtained from the thermolysis of 1 or 2 in THF at 140-degrees-C. The structures of the new clusters 2, 3 and 4 have been solved by single crystal X-ray analyses.

引用

页码：167 / 182

页数：16

共 14 条

[1] CLUSTER SYNTHESIS .19. THE SYNTHESIS OF RUTHENIUM CARBONYL CLUSTER COMPLEXES CONTAINING QUADRUPLY BRIDGING AMINOCARBYNE LIGANDS [J].

ADAMS, RD ;

BABIN, JE ;

TANNER, J .

ORGANOMETALLICS, 1988, 7 (03) :765-772

[2] CLUSTER SYNTHESES .14. THE SYNTHESES AND STRUCTURAL CHARACTERIZATIONS OF THE HIGH-NUCLEARITY SULFIDORUTHENIUM CARBONYL CLUSTER COMPOUNDS RU5(CO)14(MU-4-S)2, RU6(CO)17(MU4-S)2, AND RU7(CO)20(MU4-S)2 [J].

ADAMS, RD ;

BABIN, JE ;

TASI, M .

INORGANIC CHEMISTRY, 1987, 26 (17) :2807-2814

[3] RUTHENIUM INDUCED DEGRADATION OF TETRAMETHYLTHIOUREA TO CARBENE LIGANDS - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE CLUSTERS RU4((MU-2-CO)2(CO)9-N(MU-4-S)2[C(NME2)2]N (N=1,2) AND (MU-2-H)RU3(CO)9[MU-3-SRU3(CO)3((ETA-2-CH2NMECNME2)] [J].

BODENSIECK, U ;

STOECKLIEVANS, H ;

SUSSFINK, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 433 (1-2) :149-165

[4] THE CLUSTER ANION [RU6H(CO)15S3]- - A PLANAR HEXANUCLEAR METAL FRAMEWORK WITH ALMOST PERFECT C3V SYMMETRY [J].

BODENSIECK, U ;

STOECKLIEVANS, H ;

SUSSFINK, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (09) :1126-1127

[5]

BODENSIECK U, 1991, ANGEW CHEM, V103, P1147

[6] DODECACARBONYLTRIRUTHENIUM, RU3(CO)12 [J].

BRUCE, MI ;

JENSEN, CM ;

JONES, NL ;

SUSSFINK, G ;

HERRMANN, G ;

DASE, V .

INORGANIC SYNTHESES, 1989, 26 :259-263

[7] CHEMISTRY OF POLYNUCLEAR COMPOUNDS .24. SOME CATIONIC CARBONYL DERIVATIVES OF RUTHENIUM [J].

DEEMING, AJ ;

ETTORRE, R ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (11) :1797-&

[8] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].

GABE, EJ ;

LEPAGE, Y ;

CHARLAND, JP ;

LEE, FL ;

WHITE, PS .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387

[9] REACTION OF [MU3(CO)12], [OS3(CO)12] WITH THE CHALCONIDE ELEMENTS - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF [OS4(CO)12H2SE2] [J].

JOHNSON, BFG ;

LEWIS, J ;

LODGE, PG ;

RAITHBY, PR ;

HENRICK, K ;

MCPARTLIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (16) :719-720

[10]

JOHNSON CK, 1976, 5138 OAK RIDG NAT LA

← 1 2 →