A STUDY ON UNIT STRUCTURES OF BITUMINOUS AKABIRA COAL

被引：38

作者：

NOMURA, M

MATSUBAYASHI, K

IDA, T

MURATA, S

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, 565

来源：

FUEL PROCESSING TECHNOLOGY | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1016/0378-3820(92)90017-K

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A plausible chemical structural unit for Akabira bituminous coal is proposed. The strategy employed here was: (1) SRC (94% yield) from Akabira coal was chosen for study; (2) Possible conversion of coal constituents during SRC processing due to heating was evaluated by comparing the constituents of the SRC pyrolysate with those from extracts obtained at ambient temperature; (3) Curie point pyrolysis gave the means to estimate the constituents contained in the SRC fractions; (4) Distribution of the aromatic compounds was obtained from the pyrolysis data; (5) Distribution of aliphatic carbons was based on CP/MAS C-13-NMR data of original coal. A unit structure of C383H372O38N6 (molecular weight 5667.237) is proposed.

引用

页码：169 / 179

页数：11

共 18 条

[1] DETERMINATION OF HYDROCARBON COMPOSITION IN HIGH-BOILING AND NONDISTILLABLE COAL LIQUIDS BY LIQUID-CHROMATOGRAPHY FIELD-IONIZATION MASS-SPECTROMETRY [J].