SYNTHESIS AND STRUCTURE OF DIMETHOXYETHANE-DICHLORODIOXO-TUNGSTEN(VI) - A HIGHLY SOLUBLE DERIVATIVE OF TUNGSTEN DIOXODICHLORIDE

被引：58

作者：

DREISCH, K ^{[1
]}

ANDERSSON, C ^{[1
]}

STALHANDSKE, C ^{[1
]}

机构：

[1] LUND UNIV, CTR CHEM, DEPT INORGAN CHEM, POB 124, S-22100 LUND, SWEDEN

来源：

POLYHEDRON | 1991年 / 10卷 / 20-21期

关键词：

D O I：

10.1016/S0277-5387(00)86203-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

WOCl4 reacted with hexamethyldisiloxane at room temperature in the presence of ethyleneglycol dimethylether (dme) giving the white crystalline compound, WO2Cl2(dme) (80% yield) and its structure was determined by X-ray diffraction. The structure, which is isomorphous with MoO2Cl2(dme), is built up of discrete molecules with a distorted octahedral geometry, the tungsten atom coordinates two oxygens in cis positions, two dme oxygen atoms and two chlorine atoms.

引用

页码：2417 / 2421

页数：5

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