SYNTHESIS AND STRUCTURE OF DIMETHOXYETHANE-DICHLORODIOXO-TUNGSTEN(VI) - A HIGHLY SOLUBLE DERIVATIVE OF TUNGSTEN DIOXODICHLORIDE

被引：58

作者：

DREISCH, K ^{[1
]}

ANDERSSON, C ^{[1
]}

STALHANDSKE, C ^{[1
]}

机构：

[1] LUND UNIV, CTR CHEM, DEPT INORGAN CHEM, POB 124, S-22100 LUND, SWEDEN

来源：

POLYHEDRON | 1991年 / 10卷 / 20-21期

关键词：

D O I：

10.1016/S0277-5387(00)86203-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

WOCl4 reacted with hexamethyldisiloxane at room temperature in the presence of ethyleneglycol dimethylether (dme) giving the white crystalline compound, WO2Cl2(dme) (80% yield) and its structure was determined by X-ray diffraction. The structure, which is isomorphous with MoO2Cl2(dme), is built up of discrete molecules with a distorted octahedral geometry, the tungsten atom coordinates two oxygens in cis positions, two dme oxygen atoms and two chlorine atoms.

引用

页码：2417 / 2421

页数：5

共 26 条

[11] THE USE OF SILYLETHERS AND SILYLTHIOETHERS IN SYNTHESES OF OXOHALIDE AND THIOHALIDE COMPOUNDS OF MOLYBDENUM AND TUNGSTEN [J].

GIBSON, VC ;

KEE, TP ;

SHAW, A .

POLYHEDRON, 1990, 9 (18) :2293-2298

[12] SYNTHESES AND STRUCTURES OF NEW 2,2'-BIPYRIDINE COMPLEXES OF NIOBIUM, MOLYBDENUM, TUNGSTEN, AND RHENIUM IN HIGH OXIDATION-STATES [J].

HERRMANN, WA ;

THIEL, WR ;

HERDTWECK, E .

CHEMISCHE BERICHTE-RECUEIL, 1990, 123 (02) :271-276

[13] HIGH OXIDATION-STATE ORGANOMETALLIC CHEMISTRY, A CHALLENGE - THE EXAMPLE OF RHENIUM [J].

HERRMANN, WA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (10) :1297-1313

[14]

HERRMANN WA, 1988, COMMENTS INORG CHEM, V7, P73

[15] PREPARATION AND CRYSTAL-STRUCTURE OF 2 OXO-MOLYBDENUM COMPLEXES WITH DIMETHOXYETHANE [J].

KAMENAR, B ;

PENAVIC, M ;

KORPARCOLIG, B ;

MARKOVIC, B .

INORGANICA CHIMICA ACTA-LETTERS, 1982, 65 (06) :L245-L247

[16] METAL OXYGEN MULTIPLE BOND LENGTHS - A STATISTICAL STUDY [J].

MAYER, JM .

INORGANIC CHEMISTRY, 1988, 27 (22) :3899-3903

[17] TRANSITION-METAL COMPLEXES CONTAINING ORGANOIMIDO (NR) AND RELATED LIGANDS [J].

NUGENT, WA ;

HAYMORE, BL .

COORDINATION CHEMISTRY REVIEWS, 1980, 31 (02) :123-175

[18] SOME BIS-(TERT-BUTYLIMIDO) COMPLEXES OF THE GROUP-6 TRANSITION-METALS AND A RELATED ALKYLAMIDO DERIVATIVE [J].

NUGENT, WA ;

HARLOW, RL .

INORGANIC CHEMISTRY, 1980, 19 (03) :777-779

[19] OLEFIN METATHESIS - A MECHANISTIC STUDY OF HIGH-VALENT GROUP-6 CATALYSTS [J].

RAPPE, AK ;

GODDARD, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) :448-456

[20] A SIMPLE ROUTE TO MOLYBDENUM CARBENE CATALYSTS FOR ALKENE METATHESIS [J].

SCHOETTEL, G ;

KRESS, J ;

OSBORN, JA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (15) :1062-1063

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