SYNTHESIS AND CRYSTAL-STRUCTURE OF PRIDERITE-TYPE BARIUM VANADIUM-OXIDE BAXV8O16 (X=1.09(1))

被引：18

作者：

KANKE, Y

TAKAYAMAMUROMACHI, E

KATO, K

KOSUDA, K

机构：

[1] National Institute for Research in Inorganic Materials, Tsukuba, Ibaraki, 305

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 115卷 / 01期

关键词：

D O I：

10.1006/jssc.1995.1106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of priderite-type barium vanadium oxide, BaxV8O16 (x = 1.09(1)), was determined. Ba1.09V8O16: M(r) = 813.209, tetragonal, I4/m, a = 9.9805(2) Angstrom, c = 2.8755(1) Angstrom, V = 286.43(1) Angstrom(3), Z = 1, D-x = 4.714 Mg m(-3), mu = 9.811 mm(-1) F(000)= 373.04, T = 295 K, lambda(MoK alpha = 0.71073 Angstrom, final R = 0.016 for 580 unique observed reflections. BaxV8O16 showed no detectable Solid-solution range. (C) 1995 Academic Press, Inc.

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页码：88 / 91

页数：4

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