AGLYCONE FRAGMENTATION ACCOMPANIES BETA-GLUCOSIDASE CATALYZED-HYDROLYSIS OF SALICORTIN, A NATURALLY-OCCURRING PHENOL GLYCOSIDE

被引:19
作者
CLAUSEN, TP [1 ]
KELLER, JW [1 ]
REICHARDT, PB [1 ]
机构
[1] UNIV ALASKA,DEPT CHEM,FAIRBANKS,AK 99775
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0040-4039(00)97668-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. © 1990.
引用
收藏
页码:4537 / 4538
页数:2
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