DEALKYLATION OF THIOLS BY ALKYNE-BRIDGED DIMOLYBDENUM COMPLEXES

被引：19

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

GAY, SR ^{[1
]}

HAMILTON, T ^{[1
]}

MORRIS, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

MOLYBDENUM; CARBONYL; THIOL; ALKYNE; VINYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05448-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Mo-2(CO)(4){mu-C-2)(CO(2)Me)(2)}(eta-C5H5)(2)] with RSH produces the mu-vinyl complexes [Mo-2(CO)(2){mu-C(CO(2)Me) = CHCO(2)Me}(mu mu-SR)(eta-C5H5)(2)] when R = Et or Pr-i but, for R = (t)Bu, dealkylation of the thiol and further hydrogenation of the alkyne occurs to give [Mo-2(mu-S)(2)(mu-eta(2),eta(1),eta(1)-cis-MeO(2)CCH = CHCO(2)Me)(eta-C5H5)(2)] in which the alkene dimethyl maleate acts as a six-electron donor ligand through its double bond and the carbonyl oxygen atoms of both CO(2)Me groups. In contrast, treatment of [Mo-2(CO)(4)(mu-C(2)Me(2))(eta-C5H5)(2)] with RSH provides a convenient new route to compounds of the type [Mo-2(mu-S)(2)(mu-SR)(2)(eta-C5H5)(2)] when R = Et or(1)Pr.

引用

页码：C25 / C28

页数：4