ARYNES VIA APROTIC DIAZOTIZATION OF ANTHRANILIC ACIDS

被引：137

作者：

FRIEDMAN, L

LOGULLO, FM

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a065

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aprotic diazotization of anthranilic acids generates the corresponding benzenediazonium-2-carboxylates which decompose in situ to give arynes, carbon dioxide, and nitrogen. Moderate to excellent yields of aryne-derived products are obtained when the reaction is conducted in the presence of suitable acceptors. © 1969, American Chemical Society. All rights reserved.

引用

页码：3089 / &

共 51 条

[1] REARRANGEMENT + CLEAVAGE OF 2-ARYLIODONIOBENZOATES - TRAPPING AGENTS FOR BENZYNE
BERINGER, FM
HUANG, SJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (02) : 445 - &
[2] SPECTROSCOPIC EVIDENCE FOR GASEOUS BENZYNE
BERRY, RS
SPOKES, GN
STILES, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) : 5240 - 5241
[3] BERRY RS, 1962, J AM CHEM SOC, V84, P3750
[4] BREWER PN, 1969, J CHEM SOC C, P355
[5] PYROLYSIS OF POLYCARBONYL COMPOUNDS .I. MASS SPECTRAL AND PYROLYTIC FRAGMENTATION OF INDANETRIONE
BROWN, RFC
SOLLY, RK
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1966, 19 (06) : 1045 - &
[6] BROWN RFC, 1965, CHEM IND LONDON, V181, P1462
[7] CADOGAN JIG, 1962, J CHEM SOC, P4257
[8] OXIDATION OF 1- AND 2-AMINOBENZOTRIAZOLE
CAMPBELL, CD
REES, CW
[J]. CHEMICAL COMMUNICATIONS, 1965, (10) : 192 - &
[9] CAMPBELL CD, 1964, P CHEM SOC LONDON, P296
[10] CAVA MP, 1966, TETRAHEDRON LETT, P2947

← 1 2 3 4 5 6 →