ARYNES VIA APROTIC DIAZOTIZATION OF ANTHRANILIC ACIDS

被引:137
作者
FRIEDMAN, L
LOGULLO, FM
机构
[1] Department of Chemistry, Case Western Reserve University, Cleveland
关键词
D O I
10.1021/jo01262a065
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Aprotic diazotization of anthranilic acids generates the corresponding benzenediazonium-2-carboxylates which decompose in situ to give arynes, carbon dioxide, and nitrogen. Moderate to excellent yields of aryne-derived products are obtained when the reaction is conducted in the presence of suitable acceptors. © 1969, American Chemical Society. All rights reserved.
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页码:3089 / &
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