ARYNES VIA APROTIC DIAZOTIZATION OF ANTHRANILIC ACIDS

被引：137

作者：

FRIEDMAN, L

LOGULLO, FM

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a065

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aprotic diazotization of anthranilic acids generates the corresponding benzenediazonium-2-carboxylates which decompose in situ to give arynes, carbon dioxide, and nitrogen. Moderate to excellent yields of aryne-derived products are obtained when the reaction is conducted in the presence of suitable acceptors. © 1969, American Chemical Society. All rights reserved.

引用

页码：3089 / &

共 51 条

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