CONTRIBUTIONS TO THE CHEMISTRY OF BORON .101. FORMATION AND NMR-SPECTRA OF NIDO-2,3,4,5-TETRACARBAHEXABORANE(6) DERIVATIVES

被引：31

作者：

BERGER, HO ^{[1
]}

NOTH, H ^{[1
]}

WRACKMEYER, B ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,D-8000 MUNICH 2,FED REP GER

来源：

CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 08期

关键词：

D O I：

10.1002/cber.19791120814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

nido‐2,3,4,5‐Tetracarbahexaboran(6)‐Derivate (4, 6, 7) entstehen bei der Umsetzung von 1‐Stanna‐4‐bora‐2,5‐cyclohexadien 1 und 3‐Diethylboryl‐l‐stannacyclopentadien 5 mit Methylbordibromid. Dabei durchläuft die Reaktion mit 1 die Zwischenstufe eines 2,5‐diborylierten 1‐Bora‐3‐cyclopentens (2, 3). Die 1H‐, 11B‐ und 13C‐NMR‐Parameter der neuen Verbindungen werden im Zusammenhang mit den Daten anderer nido‐Hexacarborane diskutiert. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：2884 / 2893

页数：10

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