MULTICYCLIC RING-SYSTEMS WITH CYCLOPENTASILANES

被引：10

作者：

HENGGE, E

GSPALTL, P

SPIELBERGER, A

机构：

[1] Institut für Anorganische Chemie der Technischen Universität Graz, A-8010 Graz

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 479卷 / 1-2期

关键词：

SILICON; MERCURY; SILANE; SILANYL; CYCLOSILANE;

D O I：

10.1016/0022-328X(94)84104-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New permethylated polycyclic silanes, Nonamethylcyclopentasilanylundecamethylcyclohexasilane, 1,4-Bis(nonamethylcyclopentasilanyl)decamethylcyclohexasilane and Bis(nonamethylcyclopentasilanyl)dimethylsilane, two of them containing both, five- and six-membered rings, were synthesized for the first time and characterized by spectroscopic methods.Comparison of the longest UV-absorption maxima with literature data of compounds containing exclusively either five- or six-membered rings, shows that the influence of ringsize on UV-absorptions, as known in monocyclic silanes, is also present in polycyclic systems.

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收藏

页码：165 / 169

页数：5

相关论文

共 11 条

[1] CYCLIC POLYSILANES .4. ANION RADICALS AND SPECTROSCOPIC PROPERTIES OF PERMETHYLCYCLOPOLYSILANES [J].

CARBERRY, E ;

WEST, R ;

GLASS, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (20) :5446-&

[2] BOND-ELUCIDATIONS FOR OLIGOCYCLIC SILANES [J].

HASSLER, K ;

MITTER, FK ;

HENGGE, E ;

KRATKY, C ;

WAGNER, UG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 333 (03) :291-303

[3] OLIGOSILYL-MERCURY AND OLIGOSILYL-ALKALIMETAL COMPOUNDS [J].

HENGGE, E ;

MITTER, FK .

MONATSHEFTE FUR CHEMIE, 1986, 117 (6-7) :721-728

[4] ON THE SYNTHESIS OF PERMETHYLATED ALPHA,OMEGA-BIS(CYCLOPENTASILANYL)SILANES [J].

HENGGE, E ;

JENKNER, PK .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 560 (05) :27-34

[5] SYNTHESIS AND CHARACTERIZATION OF 1,3-DISUBSTITUTED DECAMETHYLCYCLOHEXASILANES [J].

HENGGE, E ;

EIBL, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 428 (03) :335-343

[6] A NEW WAY TO PENTACYCLOSILANE DERIVATIVES [J].

HENGGE, E ;

JENKNER, PK ;

SPIELBERGER, A ;

GSPALTL, P .

MONATSHEFTE FUR CHEMIE, 1993, 124 (10) :1005-1009

[7] SYNTHESIS, PROPERTIES AND CHARACTERIZATION OF OCTADECAMETHYLBICYCLO[4.4.0]DECASILANE [J].

JENKNER, PK ;

HENGGE, E ;

CZAPUTA, R ;

KRATKY, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 446 (1-2) :83-90

[8] PREPARATION OF NEW POLYCYCLIC METHYL SILANES [J].

MITTER, FK ;

HENGGE, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 332 (1-2) :47-52

[9] BICYCLIC SILANES FROM CYCLOSILANE-METAL DERIVATIVES [J].

MITTER, FK ;

POLLHAMMER, GI ;

HENGGE, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (1-2) :1-5

[10] PE AND UV SPECTRA OF LINEAR AND CYCLIC POLYSILANES AND ASSIGNMENT BY ABINITIO CALCULATIONS [J].

STUGER, H ;

HENGGE, E ;

JANOSCHEK, R .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1990, 48 (1-4) :189-201