SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE RHENIUM(VII) TERT-BUTYLIMIDO COMPOUND, [RE(N-TERT-BU)2(ETA-1-C5H5)]2(MU-C5H4)(MU-O)

被引：26

作者：

DANOPOULOS, AA ^{[1
]}

WILKINSON, G ^{[1
]}

WILLIAMS, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of NaC5H5 in tetrahydrofuran with a diethyl ether solution of Re(NBu(t))3Cl gives rise to a compound [Re(NBu(t))2(eta-1-C5H5)]2(mu-C5H4)(mu-O) that has fluxional eta-1-C5H5 groups, non-equivalent Bu(t)N groups and a unique bridging C5H4 group; the structure has been elucidated by X-ray crystallography.

引用

页码：181 / 182

页数：2