METAL-COATED FULLERENE MOLECULES AND CLUSTERS

被引：101

作者：

MARTIN, TP ^{[1
]}

MALINOWSKI, N ^{[1
]}

ZIMMERMANN, U ^{[1
]}

NAHER, U ^{[1
]}

SCHABER, H ^{[1
]}

机构：

[1] BULGARIAN ACAD SCI,CENT LAB PHOTOPROC,BU-1040 SOFIA,BULGARIA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 05期

关键词：

D O I：

10.1063/1.466118

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Coevaporation of C60 and an alkali metal in a gas aggregation cell yields a distribution of clusters with composition (C60)nMx with 0 less-than-or-equal-to x < 150, n = 1,2,3, and M = Li, Na, and K. For singly ionized clusters the mass peaks are strong for odd values of x but only after reaching the composition C60M7+. It is suggested that the onset of even-odd alternation marks the end of electron transfer between metal and C60 and the beginning of metal-metal bonding.

引用

页码：4210 / 4212

页数：3

共 11 条

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