NORMAL-PENTENYL ESTERS FACILITATE AN OXIDATIVE ALTERNATIVE TO THE FERRIER REARRANGEMENT - AN EXPEDITIOUS ROUTE TO SUCROSE

被引：48

作者：

LOPEZ, JC ^{[1
]}

FRASERREID, B ^{[1
]}

机构：

[1] DUKE UNIV,DEPT CHEM,PAUL M GROSS CHEM LAB,DURHAM,NC 27706

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ferrier-type reactions can now be carried out under non-acidic conditions by treating 3-n-pentenoyl glycals with iodonium dicollidinium perchlorate whereupon the terminal double bond is chemoselectively activated to furnish an allylic oxo-carbenium ion which reacts at the anomeric position with monosaccharide alcohols to afford 2,3-unsaturated disaccharides in fairly good yields.

引用

页码：94 / 96

页数：3

共 33 条

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