A MONODENTATE 1,3-DIPHENYL-2-TRIAZENO TERPYRIDINEPLATINUM(II) COMPLEX

被引：15

作者：

BAILEY, JA ^{[1
]}

CATALANO, VJ ^{[1
]}

GRAY, HB ^{[1
]}

机构：

[1] CALTECH,BECKMAN INST,PASADENA,CA 91125

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193002215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound (1,3-diphenyl-2-triazeno)(2,2',2''-terpyridine)platinum(II) perchlorate dimethylformamide solvate (1) is formed by reaction of dpt (dptH = 1,3-diphenyltriazene) and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base (NEt3). There are two independent cations in the asymmetric unit. The platinum centers have a monodentate triazeno ligand with the remaining coordination sites occupied by the terpyridine group. The crystal packing is dominated by pi-pi stacking interactions, and metal-metal interactions are conspicuously absent.

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页码：1598 / 1602

页数：5

相关论文

共 18 条

[1] A DIPHENYLFORMAMIDINATE-BRIDGED TERPYRIDINEPLATINUM(II) DIMER [J].

BAILEY, JA ;

MISKOWSKI, VM ;

GRAY, HB .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :793-796

[2] A MU-PYRAZOLYL TERPYRIDINEPLATINUM(II) DIMER [J].

BAILEY, JA ;

GRAY, HB .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1420-1422

[3] CRYSTAL-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)CHLORO-1,3-DI-P-TOLYLTRIAZENIDOPALLADIUM(II) [J].

BOMBIERI, G ;

IMMIRZI, A ;

TONIOLO, L .

INORGANIC CHEMISTRY, 1976, 15 (10) :2428-2432

[4] BIDENTATE AND MONODENTATE BONDING MODES OF 1,3-DIARYLTRIAZENIDO LIGAND IN RUTHENIUM(II) AND PLATINUM(II) COMPLEXES [J].

BROWN, LD ;

IBERS, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (06) :1597-1598

[5] STRUCTURAL STUDIES OF TRIAZENIDO COMPLEXES .2. MONODENTATE COORDINATION OF 1,3-DIPHENYLTRIAZENIDE IN CIS-BIS(TRIPHENYLPHOSPHINE)BIS(1,3-DIPHENYLTRIAZENIDO)PLATINUM(II) BENZENE SOLVATE, CIS-[PT(C6H5N3C6H5)2(P(C6H5)3)2].C6H6 [J].

BROWN, LD ;

IBERS, JA .

INORGANIC CHEMISTRY, 1976, 15 (11) :2794-2798

[6]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P149

[7] SYNTHESIS AND STRUCTURE OF A BIS[TERPYRIDINEPLATINUM(II)] COMPLEX AND ITS EVALUATION AS A METALLOINTERCALATOR [J].

DEWAN, JC ;

LIPPARD, SJ ;

BAUER, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :858-860

[8] THE NATURE OF PI-PI INTERACTIONS [J].

HUNTER, CA ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5525-5534

[9] METALLOINTERCALATION REAGENTS - SYNTHESIS, CHARACTERIZATION, AND STRUCTURAL-PROPERTIES OF THIOLATO(2,2',2''-TERPYRIDINE)PLATINUM(II) COMPLEXES [J].

JENNETTE, KW ;

GILL, JT ;

SADOWNICK, JA ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (20) :6159-6168

[10] ELECTRONIC-SPECTRA AND PHOTOPHYSICS OF PLATINUM(II) COMPLEXES WITH ALPHA-DIIMINE LIGANDS - SOLID-STATE EFFECTS .2. METAL-METAL INTERACTION IN DOUBLE SALTS AND LINEAR-CHAINS [J].

MISKOWSKI, VM ;

HOULDING, VH .

INORGANIC CHEMISTRY, 1991, 30 (23) :4446-4452