ORGANOMETALLIC MOLECULE INORGANIC SURFACE COORDINATION AND CATALYTIC CHEMISTRY - FACILE AND SELECTIVE ALKANE ACTIVATION BY SUPPORTED TETRAALYLTHORIUM

被引：26

作者：

EISEN, MS ^{[1
]}

MARKS, TJ ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 12期

关键词：

D O I：

10.1021/om00060a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The adsorption of Th(eta3-allyl), on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterically hindered.

引用

页码：3939 / 3941

页数：3

共 54 条

[1] BARTOK M, 1985, STEREOCHEMISTRY HETE, pCH1
[2] ACTIVATION OF ALKANES WITH ORGANOTRANSITION METAL-COMPLEXES
BERGMAN, RG
[J]. SCIENCE, 1984, 223 (4639) : 902 - 908
[3] HETEROGENEOUS CATALYSIS BY METALS
BOUDART, M
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1985, 30 (1-2): : 27 - 38
[4] MECHANISTIC STUDY OF PHOTOINDUCED BETA-HYDRIDE ELIMINATION - THE FACILE PHOTOCHEMICAL-SYNTHESIS OF LOW-VALENT THORIUM AND URANIUM ORGANOMETALLICS
BRUNO, JW
KALINA, DG
MINTZ, EA
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (07) : 1860 - 1869
[5] ORGANO-F-ELEMENT THERMOCHEMISTRY - METAL-LIGAND BOND DISRUPTION ENTHALPIES IN (PENTAMETHYLCYCLOPENTADIENYL)THORIUM HYDROCARBYLS, METALLACYCLES, HYDRIDES, AND DIALKYLAMIDES
BRUNO, JW
MARKS, TJ
MORSS, LR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (23) : 6824 - 6832
[6] ORGANO-F-ELEMENT THERMOCHEMISTRY - THORIUM VS URANIUM AND ANCILLARY LIGAND EFFECTS ON METAL-LIGAND BOND DISRUPTION ENTHALPIES IN BIS(PENTAMETHYLCYCLOPENTADIENYL)ACTINIDE BIS(HYDROCARBYLS) AND BIS(PENTAMETHYLCYCLOPENTADIENYL)ALKOXYACTINIDE HYDRIDES AND HYDROCARBYLS
BRUNO, JW
STECHER, HA
MORSS, LR
SONNENBERGER, DC
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) : 7275 - 7280
[7] BRUNO JW, 1986, J AM CHEM SOC, V108, P425
[8] BURWELL RL, 1985, CATALYSIS ORGANIC RE, P207
[9] THE NUMBER OF DISTINGUISHABLE CATALYTIC SITES ON RH-SILICA, PT-SILICA AND PD-SILICA CATALYSTS IN SOME RING-OPENING AND EXCHANGE-REACTIONS
BUTT, JB
BURWELL, RL
[J]. CATALYSIS TODAY, 1992, 12 (2-3) : 177 - 188
[10] THE ORGANOMETALLIC CHEMISTRY OF ALKANES
CRABTREE, RH
[J]. CHEMICAL REVIEWS, 1985, 85 (04) : 245 - 269

← 1 2 3 4 5 6 →