ORGANOMETALLIC MOLECULE INORGANIC SURFACE COORDINATION AND CATALYTIC CHEMISTRY - FACILE AND SELECTIVE ALKANE ACTIVATION BY SUPPORTED TETRAALYLTHORIUM

被引：26

作者：

EISEN, MS ^{[1
]}

MARKS, TJ ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 12期

关键词：

D O I：

10.1021/om00060a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The adsorption of Th(eta3-allyl), on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterically hindered.

引用

页码：3939 / 3941

页数：3

共 54 条

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