1ST ISOLABLE TERT-ALKYL PHENYL SELONES

被引：15

作者：

ISHII, A ^{[1
]}

DING, MX ^{[1
]}

NAKAYAMA, J ^{[1
]}

HOSHINO, M ^{[1
]}

机构：

[1] SAITAMA UNIV, FAC SCI, DEPT CHEM, URAWA, SAITAMA 338, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 12期

关键词：

D O I：

10.1246/cl.1992.2289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the dihydrazone of 2,2,6,6-tetramethyl-1,7-diphenyl-1,7-dione with Se2Cl2 in refluxing benzene in the presence of tributylamine gave the corresponding 1-oxo-7-selone and 1,7-diselone derivatives in 14 and 33% yields, respectively, while similar reaction of the dihydrazone of 2,2,5,5-tetramethyl-1,6-diphenyl-1,6-dione gave bicyclic 1,3-diselenetane (25%), 1,2,4-triselenolane (20%), and cyclohexene (12%) derivatives by intramolecular cyclizations.

引用

页码：2289 / 2292

页数：4

共 25 条

[11] SYNTHESIS AND REACTIONS OF SELENOKETONES
ISHII, A
OKAZAKI, R
INAMOTO, N
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (03) : 861 - 867
[12] SULFURIZATION OF NONENOLIZABLE DIKETONES
ISHII, A
NAKAYAMA, J
DING, MX
KOTAKA, N
HOSHINO, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (08) : 2421 - 2427
[13] REACTIVE SELENOALDEHYDES FORMED FROM SELENENYL DERIVATIVES BY 1,2-ELIMINATION AND TRAPPED INSITU AS CYCLOADDUCTS WITH CONJUGATED DIENES
KIRBY, GW
TRETHEWEY, AN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (07): : 1913 - 1922
[14] THIOKETYLS .5. ISOTROPIC ELECTRON-SPIN-RESONANCE PARAMETERS IN THIOKETYL AND SELENOKETYLS
KLAGES, CP
VOSS, J
[J]. CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (06): : 2255 - 2277
[15] PREPARATION AND CYCLO-ADDITION REACTIONS OF SELENOKETONES
MEINKE, PT
KRAFFT, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) : 8679 - 8685
[16] SYNTHESIS AND CYCLO-ADDITION REACTIVITY OF SELENOALDEHYDES
MEINKE, PT
KRAFFT, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) : 8671 - 8679
[17] GENERATION AND DIENOPHILIC REACTIVITY OF ALPHA-OXOSELENOALDEHYDES AND KETONES
NAKAYAMA, J
AKIMOTO, K
NIIJIMA, J
HOSHINO, M
[J]. TETRAHEDRON LETTERS, 1987, 28 (38) : 4423 - 4426
[18] NEW ASPECTS OF ORGANOSELENIUM COMPOUNDS CONTAINING GROUP 14 ELEMENTS
OKAZAKI, R
TOKITOH, N
ISHII, A
ISHII, N
MATSUHASHI, Y
MATSUMOTO, T
SUZUKI, H
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 67 (1-4): : 49 - 66
[19] A NEW, CONVENIENT SYNTHESIS OF SELENOKETONES
OKAZAKI, R
ISHII, A
INAMOTO, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (23) : 1429 - 1430
[20] 2,4,6-TRI-TERT-BUTYLSELENOBENZALDEHYDE, THE 1ST STABLE SELENOALDEHYDE
OKAZAKI, R
KUMON, N
INAMOTO, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) : 5949 - 5951

← 1 2 3 →