COBALT COMPLEXES WITH PNICOGEN (PHOSPHINE OR PYRIDINE) AND THIOLATO LIGANDS - SYNTHESES, X-RAY CRYSTAL-STRUCTURES AND SPECTROSCOPIC CHARACTERIZATION

被引：26

作者：

KANG, BS ^{[1
]}

XU, YJ ^{[1
]}

PENG, JH ^{[1
]}

WU, DX ^{[1
]}

CHEN, XT ^{[1
]}

HU, YH ^{[1
]}

HONG, MC ^{[1
]}

LU, JX ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

来源：

POLYHEDRON | 1993年 / 12卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81539-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed pnicogen and thiolato mononuclear cobalt complexes, CO(SR)2(PBun3)2 [R = Ph (1); R = Stolyl-p (2)] and Co(mpo)2L [L = PBun3 (3); L = Py (4)], have been synthesized and studied spectroscopically. The complexes 1 and 2 are tetrahedral, as determined by magnetic susceptibility studies. The structures of 3 and 4 were determined by X-ray diffraction. The cobalt(II) ions in both 3 and 4 are in a square-pyramidal environment with the two trans-oriented mpo ligands in the basal plane and the pnicogen group in the axial position.

引用

页码：871 / 878

页数：8

共 23 条

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[23] SYNTHESES AND STEREOCHEMISTRY OF DICOBALT(II) COMPLEXES [CO2(DPPM)(MU-SR)2(SR)2] (DPPM = PH2PCH2PPH2 - R = C6H5, M-C6H4CH3, P-C6H4CH3 AND P-C6H4-TC4H9) AND [CO2(DPPE)(MU-SPH)3(SPH)] (DPPE = PH2PCH2CH2PPH2) [J].

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POLYHEDRON, 1991, 10 (06) :553-560

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