STEREOCONTROL IN CYCLIZATION OF DIOXOLANYL RADICALS

被引:24
作者
BATSANOV, AS [1 ]
BEGLEY, MJ [1 ]
FLETCHER, RJ [1 ]
MURPHY, JA [1 ]
SHERBURN, MS [1 ]
机构
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 10期
关键词
D O I
10.1039/p19950001281
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Appropriate nitrate esters are cleaved under photolytic or thermal (tributyltin radical) conditions to yield dioxolanyl radicals which undergo stereoselective cyclisation to heterocyclic products. The X-ray crystallographic structures for compounds 30a and 35 are reported.
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页码:1281 / 1294
页数:14
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