RADICAL CYCLIZATION OF DIENES AND ENYNES USING TOLSO2SEPH

被引:25
作者
BRUMWELL, JE
SIMPKINS, NS
TERRETT, NK
机构
[1] UNIV NOTTINGHAM,DEPT CHEM,UNIV PK,NOTTINGHAM NG7 2RD,ENGLAND
[2] PFIZER LTD,SANDWICH CT13 9NJ,KENT,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)77533-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of a number of 1,6-diene or enyne systems with TolSO2SePh, under free radical conditions, results in selenosulphonylation with concommitant C-C bond formation, to give cyclised alkyl or vinyl sulphones containing the synthetically useful phenylselenyl functionality.
引用
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页码:1219 / 1222
页数:4
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