INVESTIGATIONS OF HALONIUM IONS IN THE GAS-PHASE

被引：15

作者：

HOLLIS, J

TEDDER, JM

WALKER, GS

机构：

[1] CSIRO,DIV COAL & ENERGY TECHNOL,PRIVATE MAIL BAG 7,MENAI 2234,NSW,AUSTRALIA

[2] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1991年 / 08期

关键词：

D O I：

10.1039/p29910001187

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mechanisms involved in the formation of monomethyl halonium and dimethyl halonium ions in the gas phase have been investigated using a triple quadrupole mass spectrometer and a quinqua quadrupole mass spectrometer. The results indicate that the mechanism for formation of the halonium ions is analogous to the S(N)2 nucleophilic addition with elimination mechanism previously reported for the formation of oxonium ions.

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页码：1187 / 1194

页数：8

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