DIASTEREOSELECTIVE ALLYLATION OF CHIRAL IMINES - NOVEL APPLICATION OF ALLYLCOPPER REAGENTS TO THE ENANTIOSELECTIVE SYNTHESIS OF HOMOALLYL AMINES

被引：47

作者：

BOCOUM, A ^{[1
]}

BOGA, C ^{[1
]}

SAVOIA, D ^{[1
]}

UMANIRONCHI, A ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,VIA SELMI 2,I-40126 BOLOGNA,ITALY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)79669-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of allylcopper reagents to imines derived from S-valine occurs with excellent diastereoselectivity (e.e. 98%).

引用

收藏

页码：1367 / 1370

页数：4

相关论文

共 7 条

[1] BOGA C, 1990, TETRAHEDRON ASYMMETR, P291
[2] LASCHAT S, 1990, SYNLETT, P51
[3] NEW METHODOLOGY FOR CONJUGATE ADDITIONS OF ALLYLIC LIGANDS TO ALPHA,BETA-UNSATURATED KETONES - SYNTHETIC AND SPECTROSCOPIC STUDIES
LIPSHUTZ, BH
ELLSWORTH, EL
DIMOCK, SH
SMITH, RAJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) : 4404 - 4410
[4] A NOVEL TI(0) INDUCED ALLYLATION OF IMINES IN A TICL4 (CAT) AL BIMETAL SYSTEM - CHIRALITY TRANSFER OF L-VALINE TO HOMOALLYLAMINE
TANAKA, H
INOUE, K
POKORSKI, U
TANIGUCHI, M
TORII, S
[J]. TETRAHEDRON LETTERS, 1990, 31 (21) : 3023 - 3026
[5] TANAKA H, 1989, TETRAHEDRON LETT, P4161
[6] VERY HIGH 1,2-ASYMMETRIC INDUCTION IN THE REACTION OF ALLYL-9-BBN WITH CERTAIN IMINES - EVIDENCE FOR A STEREOELECTRONIC EFFECT TO ENHANCE THE CRAM SELECTIVITY
YAMAMOTO, Y
KOMATSU, T
MARUYAMA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) : 5031 - 5033
[7] VERY HIGH 1,2-ASYMMETRIC AND 1,3-ASYMMETRIC INDUCTION IN THE REACTIONS OF ALLYLIC BORON-COMPOUNDS WITH CHIRAL IMINES
YAMAMOTO, Y
NISHII, S
MARUYAMA, K
KOMATSU, T
ITO, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) : 7778 - 7786