GUEST-DEPENDENT [CD(CN)2]N HOST STRUCTURES OF CADMIUM CYANIDE ALCOHOL CLATHRATES - 2 NEW [CD(CN)2]N FRAMEWORKS FORMED WITH PRNOH AND PRIOH GUESTS

被引:61
作者
KIM, J
WHANG, D
LEE, JI
KIM, K
机构
[1] POHANG UNIV SCI & TECHNOL,DEPT CHEM,POB 125,POHANG 790600,SOUTH KOREA
[2] POHANG UNIV SCI & TECHNOL,CTR BIOFUNCT MOLEC,POHANG 790600,SOUTH KOREA
关键词
D O I
10.1039/c39930001400
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystallization of Cd(CN)2 from the geometric isomers of propanol, Pr(n)OH and Pr(i)OH, yielded new cadmium cyanide clathrates whose [Cd(CN)2]n frameworks are topologically and geometrically different not only from those of all the previously known cadmium cyanide clathrates but also from each other: the former has both hexagonal and pentagonal channels whereas the latter has only pentagonal channels.
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页码:1400 / 1402
页数:3
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