SYNTHESIS OF HEXAOXADIAMANTANES

被引：13

作者：

VOGL, O

ANDERSON, BC

SIMONS, DM

机构：

[1] Central Research Department, Elastomer Chemicals Department, E. I. du Pont de Nemours and Company, Wilmington, Delaware 19898, Experimental Station

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a044

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of scyllitol with triethyl orthoformate in DMSO and other solvents has investigated. The reaction yields a polymeric intermediate which can be pyrolyzed to give hexaoxadiamantane (HOD). No apically substituted HOD homologs were obtained from scyllitol and ortho esters of higher acids. Scyllitol underwent reaction with trimethyl phosphite to give 1,6-diphosphahexaoxadiamantane. © 1969, American Chemical Society. All rights reserved.

引用

页码：204 / +

页数：1

共 11 条

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