STUDIES OF POROUS POLYACENIC SEMICONDUCTORS TOWARD APPLICATION .1. PREPARATION AND STRUCTURAL-ANALYSIS

被引:23
作者
YATA, S
HATO, Y
SAKURAI, K
SATAKE, H
MUKAI, K
TANAKA, K
YAMABE, T
机构
[1] KYOTO UNIV,FAC ENGN,DEPT HYDROCARBON CHEM,SAKYO KU,KYOTO 606,JAPAN
[2] KYOTO UNIV,FAC ENGN,DIV MOLEC ENGN,SAKYO KU,KYOTO 606,JAPAN
[3] KANEBO LTD,DEV LABS,MIYAKOJIMA KU,OSAKA 534,JAPAN
关键词
D O I
10.1016/0379-6779(90)90101-P
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A detailed description of the preparation of porous polyacenic semiconductor (PAS) materials is reported. The structural analyses of these materials by the combination of mercury porosimetry and adsorption isotherm measurements have revealed that there are two kinds of pores distinguished by their radii therein. The smaller pore (micropore) size of the porous PAS sample prepared by specific pyrolysis temperature is estimated as about 5 Å being much larger than those of active carbons and, hence, rationalizes the 'dopability' of the present sample with bulky dopants already reported. © 1990.
引用
收藏
页码:169 / 175
页数:7
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