SMCL3-CATALYZED ELECTROCHEMICAL REDUCTIVE ALLYLATION OF KETONES

被引：16

作者：

HEBRI, H ^{[1
]}

DUNACH, E ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] CNRS,ELECTROCHIM CATALYSE & SYNTHESE ORGAN LAB,2 RUE H DUNANT,F-94320 THIAIS,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)60322-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of homoallylic alcohols was prepared in moderate to good yields from allyl chlorides and ketones, through an electrochemical method using SmCl3 as the catalyst precursor. The electrosyntheses were carried out in undivided cells fitted with a consumable magnesium anode.

引用

页码：1475 / 1478

页数：4

共 15 条

[11] NEW PREPARATIONS OF LANTHANIDE ALKOXIDES AND THEIR CATALYTICAL ACTIVITY IN MEERWEIN-PONNDORF-VERLEY-OPPENAUER REACTIONS [J].

NAMY, JL ;

SOUPPE, J ;

COLLIN, J ;

KAGAN, HB .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (11) :2045-2049

[12] ELECTROSYNTHESIS OF ALCOHOLS FROM ORGANIC HALIDES AND KETONES OR ALDEHYDES [J].

SIBILLE, S ;

DINCAN, E ;

LEPORT, L ;

PERICHON, J .

TETRAHEDRON LETTERS, 1986, 27 (27) :3129-3132

[13] SAMARIUM DIIODIDE AS COUPLING AGENT BETWEEN ALDEHYDES AND ORGANIC HALIDES FOR THE SYNTHESIS OF HOMOALLYLIC AND HOMOBENZYLIC ALCOHOLS [J].

SOUPPE, J ;

NAMY, JL ;

KAGAN, HB .

TETRAHEDRON LETTERS, 1982, 23 (34) :3497-3500

[14] SOME ORGANIC-REACTIONS PROMOTED BY SAMARIUM DIIODIDE [J].

SOUPPE, J ;

DANON, L ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :227-236

[15] GRIGNARD-TYPE ALLYLATION OF CARBONYL-COMPOUNDS IN METHANOL BY THE ELECTROCHEMICALLY RECYCLED ALLYLTIN REAGENT [J].

UNEYAMA, K ;

MATSUDA, H ;

TORII, S .

TETRAHEDRON LETTERS, 1984, 25 (52) :6017-6020

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