A GENERAL PROCEDURE FOR THE SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES BY NITRIC-ACID - TETRABROMOAURATE(III) CATALYST IN A BIPHASIC SYSTEM

被引：34

作者：

GASPARRINI, F

GIOVANNOLI, M

MISITI, D

NATILE, G

PALMIERI, G

机构：

[1] DIPARTIMENTO FARM CHIM,I-70126 BARI,ITALY

[2] DIPARTIMENTO SCI CHIM,I-62032 CAMERINO,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 04期

关键词：

D O I：

10.1021/jo00291a043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetrabromoaurate(III) is an efficient catalyst for the oxidation of sulfides to sulfoxides by nitric acid in a biphasic system (nitromethane/water). The system is selective and can be applied to the oxidation of any type of dialkyl and alkyl aryl sulfide and also of diaryl sulfides activated by electron-releasing substituents. The nature of the active species has been investigated in relation to the mechanistic aspects. © 1990, American Chemical Society. All rights reserved.

引用

页码：1323 / 1328

页数：6

共 44 条

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