SELECTIVITY AND MECHANISM IN CATALYTIC ASYMMETRIC-SYNTHESIS

被引：123

作者：

BROWN, JM

机构：

来源：

CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 01期

关键词：

D O I：

10.1039/cs9932200025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The utility of homogeneous catalysis in organic synthesis rests on a few key reactions, among which hydrogenation and other reductive procedures feature prominently. The review covers work on asymmetric hydrogenation, directed hydrogenation, transfer hydrogenation, and hydroboration carried out in Oxford in the last few years, and highlights the way in which mechanistic experiments can augment the synthetic utility of catalysis.

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页码：25 / 41

页数：17

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