HYDROACYLATION OF ALKYL VINYL KETONES AND ACRYLIC ESTERS USING ORGANOTETRACARBONYLFERRATES - SYNTHESIS OF 1,4-DICARBONYL COMPOUNDS

被引：20

作者：

YAMASHITA, M

TASHIKA, H

UCHIDA, M

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 05期

关键词：

D O I：

10.1246/bcsj.65.1257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl vinyl ketones and acrylic esters were hydroacylated with organotetracarbonylferrates to the corresponding 1,4-diketones and 4-oxo carboxylic acid derivatives in good yield in dipolar aprotic solvents such as N,N-dimethylacetamide. Addition of 18-crown-6-improved the yield. cis-Jasmone and gamma-jasmolactone were synthesized by use of these reactions.

引用

页码：1257 / 1261

页数：5

共 18 条

[11]

MCMURRY E, 1980, TETRAHEDRON LETT, P4687

[12]

MIYAKOSHI T, 1988, J JPN OIL CHEM SOC Y, V37, P19

[13] SYNTHESIS OF 1,4-DIKETONES BY REACTION OF LITHIUM AROYLTRICARBONYLNICKELATES WITH ACETYLENES [J].