PHENYLTHIO RADICAL CATALYZED REARRANGEMENT OF ACETOXYALKENYL EPOXIDES TO ACETOXYALKENYL CYCLOPENTANOLS

被引：41

作者：

RAWAL, VH

KRISHNAMURTHY, V

机构：

[1] Department of Chemistry, The Ohio State University Columbus

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期

关键词：

PHENYLTHIO RADICAL; ENOLACETATE; RADICAL CATALYZED CYCLIZATION; EPOXIDE FRAGMENTATION;

D O I：

10.1016/S0040-4039(00)92657-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exposure of cyclic acetoxyalkenyl epoxides to a catalytic amount of PhS. initiates a tandem radical induced epoxide fragmentation-H. abstraction-cyclization process that results in a net isomerization to bicyclic enolacetates.

引用

页码：3439 / 3442

页数：4

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