OPTICAL RESOLUTION BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY (HPLC) USING POLYSACCHARIDE DERIVATIVES AS CHIRAL STATIONARY PHASES

被引：11

作者：

OKAMOTO, Y

KAIDA, Y

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1993年 / 51卷 / 01期

关键词：

OPTICAL RESOLUTION; HPLC; CHIRAL STATIONARY PHASE; CELLULOSE TRIBENZOATE; CELLULOSE TRIS(PHENYLCARBAMATE); AMYLOSE TRIS(PHENYLCARBAMATE); CELLULOSE TRIS(3,5-DIMETHYLPHENYLCARBAMATE);

D O I：

10.5059/yukigoseikyokaishi.51.41

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polysaccharides such as cellulose and amylose are the most accessible optically active polymers. The polysaccharides themselves show rather low chiral recognition, but their derivatives show high chiral recognition and afford useful chiral stationary phases (CSPs) for HPLC. In this review, optical resolution by cellulose esters, especially benzoates, and by various phenylcarbamates of cellulose and amylose is discussed. Chiral recognition abilities of aralkylcarbamates of cellulose and amylose are also evaluated.

引用

页码：41 / 53

页数：13

共 134 条

[1]

ABOULENEIN HY, 1990, ANAL LETT, V23, P973

[2] DIRECT SEPARATION AND OPTIMIZATION OF TIMOLOL ENANTIOMERS ON A CELLULOSE TRIS-3,5-DIMETHYLPHENYLCARBAMATE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC CHIRAL STATIONARY PHASE [J].