CONDENSATION OF ATMOSPHERIC GASES ON COLD SURFACES

被引:12
作者
BENTLEY, PD
HANDS, BA
机构
来源
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1978年 / 359卷 / 1698期
关键词
D O I
10.1098/rspa.1978.0045
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Data for the deposition of argon, nitrogen and carbon dioxide on cold, metal surfaces are considered in detail. It is concluded that argon and nitrogen deposit when the incident gas pressure equals the sublimation pressure at the respective surface temperature, and growth therefore proceeds without any significant intermediate nucleation barrier. Carbon dioxide, however, requires considerable supersaturation of the gaseous phase and consequently bulk deposition is inhibited by a nucleation barrier. The results are analyzed with a view to determining the critical nucleus size and the adsorption energy.
引用
收藏
页码:319 / 343
页数:25
相关论文
共 46 条
[11]   NUCLEATION ON SUBSTRATES FROM VAPOUR PHASE [J].
FRANKL, DR ;
VENABLES, JA .
ADVANCES IN PHYSICS, 1970, 19 (80) :409-&
[12]   THE SOLID-SOLUTION KRYPTON-XENON FROM 90-DEGREES-K TO 120-DEGREES-K, THE VAPOR PRESSURES OF ARGON, KRYPTON AND XENON [J].
FREEMAN, MP ;
HALSEY, GD .
JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (07) :1119-1125
[13]   Theory of the adsorption and related occurrences [J].
Frenkel, J .
ZEITSCHRIFT FUR PHYSIK, 1924, 26 :117-138
[14]  
GIAQUE WF, 1937, J CHEM PHYS, V5, P45
[15]   CRYOPUMPED AERODYNAMIC MOLECULAR-BEAM APPARATUS [J].
HANDS, BA ;
BENTLEY, PD .
VACUUM, 1977, 27 (02) :53-59
[16]  
HEALD JH, 1968, AEDCTR68110
[17]  
HIRTH JP, 1963, PROGR MATERIALS SCI, V11
[18]  
HONIG PE, 1960, RCA REV, V21, P360
[19]   New determination of the lattice constant of carbon dioxide [J].
Keesom, WH ;
Kohler, JWL .
PHYSICA, 1934, 1 :167-174
[20]   The lattice constant and expansion coefficient of solid carbon dioxide [J].
Keesom, WH ;
Kohler, JWL .
PHYSICA, 1934, 1 :655-658