ALKYLIRON AND ALKYLCOBALT REAGENTS .4. ALDEHYDE-SELECTIVE CYANOALKYLATION WITH CYANOALKYL DERIVATIVES OF IRON(II) AND OTHER TRANSITION-METALS

被引：26

作者：

KAUFFMANN, T

KIEPER, H

PIEPER, H

机构：

[1] Organisch-Chemisches Institut, Universität Münster, Munster, W-4400

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 04期

关键词：

ORGANOIRON COMPOUNDS; IRON(II) ALKYLS; CYANOALKYLATION;

D O I：

10.1002/cber.19921250422

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the transfer of the cyanomethyl residue with high aldehyde vs. ketone selectivity, the Fe reagent 3a is a good alternative to the known Ti reagent 1 a[2], whereas analogous reagents with the metals Mn, Co, Ni or Cu are unfavorable. For the aldehyde- vs. ketone-selective transfer of the branched residues 1-cyanoethyl and cyanoisopropyl, the Fe reagents 3b and 3c are distinctly better than the Ti reagents 1b and 1c.

引用

页码：899 / 905

页数：7

共 28 条

[21] PIEPER H, 1985, THESIS U MUNSTER
[22] REETZ MT, 1981, CHEM IND-LONDON, P541
[23] REETZ MT, 1982, TOP CURR CHEM, V106, P1
[24] REETZ MT, 1986, ORGANOTITANIUM REAGE, P78
[25] PREPARATION OF LITHIUM TETRAMETHYLOFERRATE(II), LI2[FE(CH3)4]
SPIEGL, HJ
GROH, G
BERTHOLD, HJ
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 398 (03): : 225 - 230
[26] CONTRIBUTIONS TO CHEMISTRY OF TRANSITION-METAL ALKYL-COMPOUNDS .25. PREPARATION AND PROPERTIES OF [TI(CH2CN)4.2THF]N
THIELE, KH
KRUGER, H
KOHLER, E
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 437 (DEC): : 210 - 212
[27] CLAISEN-SCHMIDT CONDENSATION OF ACETONITRILE WITH AROMATIC CARBONYL COMPOUNDS
UCHIDA, A
SAITO, S
MATSUDA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1969, 42 (10) : 2989 - +
[28] WATT DS, 1974, TETRAHEDRON LETT, P707

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