THE FIRST OLEFIN-SUBSTITUTED PEROXOMOLYBDENUM COMPLEX - INSIGHT INTO A NEW MECHANISM FOR THE MOLYBDENUM-CATALYZED EPOXIDATION OF OLEFINS

被引：156

作者：

THIEL, WR

PRIERMEIER, T

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, D-85747

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 16期

关键词：

CATALYSIS; EPOXIDATIONS; MOLYBDENUM COMPOUNDS;

D O I：

10.1002/anie.199517371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

What is the source of the epoxide oxygen in the Mo‐catalyzed epoxidation of olefins? The olefinic side chain CH2CHCH2 of the isolated complex 1 (structure shown on the right) is epoxidized only on addition of hydroperoxides. Thus in complex 1, in contrast to previously proposed mechanisms for the title reaction, an oxygen atom from the η2‐peroxo ligand is not transferred to the olefin. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1737 / 1738

页数：2

共 23 条

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