SYNTHESIS OF LINKED METAL ACETYLIDE COMPLEXES FOR NONLINEAR OPTICS

被引：59

作者：

DAVIES, SJ ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

KHAN, MS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 401卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86238-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnC = CPh affords the known species [(CO)5Mn(C = CPh)] (2), whereas reaction between 1 and Me3SnC = CRC = CSnMe3 (R = p-C6H4-C6H4) gives the bimetallic complex [(CO)5MnC = CRC = CSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnC = CRC = CMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnC = CRC = CPd(PBu3)2Cl] (5).

引用

页码：C43 / C45

页数：3