A CYCLIC HEXAIRON(III) COMPLEX WITH AN OCTAHEDRALLY COORDINATED SODIUM-ION AT THE CENTER, AN EXAMPLE OF THE [12]METALLACROWN-6 STRUCTURE TYPE

被引：121

作者：

CANESCHI, A

CORNIA, A

LIPPARD, SJ

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

[2] UNIV FLORENCE,DIPARTIMENTO CHIM,I-50144 FLORENCE,ITALY

[3] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 04期

关键词：

COMPLEXES WITH OXYGEN LIGANDS; HOST-GUEST CHEMISTRY; IRON COMPOUNDS; MAGNETIC PROPERTIES;

D O I：

10.1002/anie.199504671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A crown composed purely of inorganic components forms the core of complex cation 1. Interest in this polyiron ion is based on its potential relevance to intermediates in the formation of the ferritin core and the hydrolytic polymerization of FeIII salts. The crown structure is supported by the inclusion of a sodium ion within the Fe6O6 ring. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：467 / 469

页数：3

共 59 条

[41] POLYIRON OXO CHEMISTRY AT THE MOLECULAR SOLID-STATE BOUNDARY - SYNTHESIS, STRUCTURE, AND MAGNETIC AND MOSSBAUER PROPERTIES OF [FE(16)MO(10)(OH)(10)(O(2)CPH)(20)] COMPLEXES, M=MN, FE, OR CO
MICKLITZ, W
MCKEE, V
RARDIN, RL
PENCE, LE
PAPAEFTHYMIOU, GC
BOTT, SG
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) : 8061 - 8069
[42] Mller U, 1981, ANGEW CHEM, V93, P697
[43] HEXAMERIC MOLYBDENUM TETRACHLORIDE
MULLER, U
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (08): : 692 - 693
[44] IRON OXO AGGREGATION - FE3 TO FE6 - SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF THE HEXANUCLEAR DICATION [FE(MU-4-O)2(MU-2-OME)8(OME)4(TREN)2]2+, A SOLUBLE, CRYSTALLINE MODEL OF IRON OXO HYDROXO NANOPARTICLES, THE CORE OF FERRITIN AND RUST FORMATION
NAIR, VS
HAGEN, KS
[J]. INORGANIC CHEMISTRY, 1992, 31 (20) : 4048 - 4050
[45] NAIR VS, 1993, 206TH ACS NAT M CHIC
[46] PAPEFTHYMIOU GC, 1992, PHYS REV B, V46, P10366
[47] A NEW ROUTE TO IRON-SULFUR CLUSTERS - SYNTHESIS AND STRUCTURE OF [(C2H5)4N]2FE6S6I6
SAAK, W
HENKEL, G
POHL, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (02): : 150 - 151
[48] Saak W., 1984, ANGEW CHEM, V96, P153
[49] SCHNEIDER W, 1988, CHIMIA, V42, P9
[50] Schneider W., 1984, COMMENTS INORG CHEM, V3, P205, DOI DOI 10.1080/02603598408078138

← 1 2 3 4 5 6 →