ORIENTATION OF THE ISOPROPYL GROUPING IN ISOPROPYL CHLOROFORMATE AND ISOPROPYL CYANOFORMATE

被引：2

作者：

VANDERVEKEN, BJ

LIEFOOGHE, HH

机构：

[1] Department of Chemistry, RUCA, B2020 Antwerp

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 328卷

关键词：

D O I：

10.1016/0022-2860(94)08371-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vapour phase infrared contours of the carbonyl stretching of five differently deuterated derivatives of isopropyl chloroformate, and of three differently deuterated derivatives of isopropyl cyanoformate have been investigated. Simulations using rigid asymmetric top calculations of the observed contours indicate that the COCH dihedral angle is close to 20 degrees in both the chloroformate and the cyanoformate ester.

引用

页码：211 / 220

页数：10

共 14 条

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