HYDROXYLATION OF ALKANES WITH MOLECULAR-OXYGEN CATALYZED BY A NEW RUTHENIUM-SUBSTITUTED POLYOXOMETALATE, [WZNRU(2)(III)(OH)(H2O)(ZNW9O34)2](11-)

被引：89

作者：

NEUMANN, R

KHENKIN, AM

DAHAN, M

机构：

[1] Casali Institute of Applied Chemistry, Graduate School of Applied Science, The Hebrew University of Jerusalem, Jerusalm

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

OXYGEN ACTIVATION; POLYOXOMETALATES; RUTHENIUM COMPOUNDS;

D O I：

10.1002/anie.199515871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly selective aerobic hydroxylation of tertiary carbon centers in alkanes is catalyzed by the title polyoxometalate under mild reaction conditions [Eq. (a)]. This is of great significance, in particular in the search for ways to activate molecular oxygen in the oxidation of hydrocarbons. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1587 / 1589

页数：3

共 16 条

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