SUBSTITUENT DEPENDENCE OF LITHIUM COORDINATION OF PHOSPHINOMETHANIDES AND MOLECULAR-STRUCTURE OF (TMEDA)LI[C(PPH(2))2(SIME(3))] AND ((THF)LI[CH(PME(2))(2)])(2)

被引：21

作者：

KARSCH, HH

GRAUVOGL, G

MIKULCIK, P

BISSINGER, P

MULLER, G

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

LITHIUM; DIPHOSPHINOMETHANIDE; SILYL;

D O I：

10.1016/0022-328X(94)87037-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structures of the title compounds are closely related to other lithium diphosphinomethanides. Characteristic differences may be related due to the different substitution pattern of the diphosphinomethanide ligands.

引用

页码：65 / 71

页数：7

共 12 条

[1]

BRAUER DJ, 1986, J ORGANOMET CHEM, V299, P137

[2] FUNCTIONAL DERIVATIVES OF TRIMETHYLPHOSPHINE .6. "LITHIUM-DIMETHYLPHOSPHINOMETHANIDE, (CH3)2PCH2LI, TETRAORGANODIPHOSPHINOMETHANES, R2PCH2P(CH3)2, AND TRIS(DIMETHYLPHOSPHINOMETHYL)PHOSPHINE, P[CH2P(CH3)2]3 [J].

KARSCH, HH ;

SCHMIDBAUR, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (07) :762-767

[3] ZIRCONOCENE DERIVATIVES WITH PHOSPHINOMETHANIDE LIGANDS - METAL-PROMOTED LIGAND METALATIONS - TUNING OF REGIOSELECTIVITY AND FORMATION OF NOVEL ZIRCONAPHOSPHAHETEROCYCLES [J].

KARSCH, HH ;

GRAUVOGL, G ;

KAWECKI, M ;

BISSINGER, P .

ORGANOMETALLICS, 1993, 12 (07) :2757-2766

[4] COMPLEXES WITH PHOSPHINOMETHANE AND PHOSPHINOMETHANIDE LIGANDS .17. LITHIUM PHOSPHINOMETHANIDES - 2 NOVEL STRUCTURES [J].

KARSCH, HH ;

ZELLNER, K ;

MIKULCIK, P ;

LACHMANN, J ;

MULLER, G .

ORGANOMETALLICS, 1990, 9 (01) :190-194

[5] COMPLEXES WITH PHOSPHINOMETHANE AND PHOSPHINOMETHANIDE LIGANDS .16. CO-LIGANDS AND SUBSTITUENT-DEPENDENCE OF THE COORDINATION OF DIPHOSPHINOMETHANIDE LIGANDS [(R2P)2CX]- TO LI+ AND CRYSTAL-STRUCTURES OF ((THF)LI[(PH2P)2CH])2, ((THF)LI[(ME2P)2C(SIME3)])2 AND ((TMEDA)LI[(ME2P)2C(SIME3)]) [J].

KARSCH, HH ;

DEUBELLY, B ;

MULLER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 352 (1-2) :47-59

[6] INFLUENCE OF CO LIGANDS ON LITHIUM COORDINATION OF PHOSPHINOMETHANIDES AND MOLECULAR-STRUCTURE OF ((THF)LI[C(SIME3)2(PME2)])2 [J].

KARSCH, HH ;

ZELLNER, K ;

GAMPER, S ;

MULLER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 414 (02) :C39-C44

[7]

KARSCH HH, 1984, Z NATURFORSCH B, V39, P1518

[8] ZIRCONOCENE DERIVATIVES WITH PHOSPHINOMETHANIDE LIGANDS - SYNTHESIS, REACTIONS, AND MOLECULAR-STRUCTURES OF CP2ZR(CL)[C(PME2)(X)(Y)] (X = H, Y = PME2, SIME3 X = Y = SIME3) [J].

KARSCH, HH ;

GRAUVOGL, G ;

DEUBELLY, B ;

MULLER, G .

ORGANOMETALLICS, 1992, 11 (12) :4238-4245

[9] ZIRCONOCENE DERIVATIVES WITH DIPHOSPHINOMETHANIDE LIGANDS - SYNTHESES OF THE CHELATE COMPLEXES CP2(CL)ZR[(R2P)2CX] AND X-RAY STRUCTURE DETERMINATIONS FOR R = ME, PH AND X = SIME3 [J].

KARSCH, HH ;

DEUBELLY, B ;

GRAUVOGL, G ;

LACHMANN, J ;

MULLER, G .

ORGANOMETALLICS, 1992, 11 (12) :4245-4249

[10]

KARSCH HH, 1986, ANGEW CHEM, V98, P832

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