A KINETIC METHOD FOR DETERMINATION OF REDOX POTENTIALS - OXIDATION OF TETRAARYLBORATES

被引：30

作者：

MURPHY, S

SCHUSTER, GB

机构：

[1] Department of Chemistry, University of Illinois, Roger Adams Laboratory, Urbana

[2] School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 02期

关键词：

D O I：

10.1021/j100002a011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method to obtain the oxidation potentials of tetraarylborates was developed which uses electron transfer rate constant measurements. The keys to the method are choosing appropriate electron accepters, using Marcus theory of electron transfer, and independently determining the maximum rate for electron transfer. When these criteria are met, oxidation potentials of reasonable accuracy and precision are obtained.

引用

页码：511 / 515

页数：5

共 14 条

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