ACTIVATION OF H-2 BY CHLOROCARBONYLBIS(TRIMETHYLPHOSPHINE)RHODIUM(I) LABILIZES CO AND PRODUCES THE NEW BINUCLEAR COMPLEX H(CL)RH(PME3)2(MU-H)(MU-CL)RH(PME3)(CO)

被引：29

作者：

DUCKETT, SB

EISENBERG, R

GOLDMAN, AS

机构：

[1] UNIV ROCHESTER,DEPT CHEM,ROCHESTER,NY 14627

[2] RUTGERS UNIV,DEPT CHEM,NEW BRUNSWICK,NJ 08903

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 15期

关键词：

D O I：

10.1039/c39930001185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative addition of H-2 to [RhCl(CO)(PMe3)2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

引用

页码：1185 / 1187

页数：3

共 19 条

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