A DIRUTHENIUM(III)-MU-OXO COMPLEX WITH AMINO-ACID BRIDGES AND ITS OXIDATIVE DEAMINATION IN THE PRESENCE OF OXYGEN

被引：9

作者：

KHAN, MMT

HUSSAIN, A

MOIZ, MA

CHATTERJEE, D

THORAT, RB

机构：

[1] Discipline of Coordination Chemistry and Homogeneous Catalysis, Central Salt and Marine Chemicals Research Institute, Bhavnagar

来源：

POLYHEDRON | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)84579-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A stable diamagnetic complex of the type [(Ru(III)edta) 2-mu-(amino-acidato)-2-mu-oxo]6-is reported. The amino acid bridge in the presence of oxygen undergoes oxidative deamination. as shown by the formation of an alpha-keto acid and the liberation of NH3. The reaction is catalytic.

引用

页码：1437 / 1441

页数：5

共 14 条

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