CONSTRUCTION OF THE C46-C55 FRAGMENT OF CIGUATOXIN

被引：29

作者：

OKA, T ^{[1
]}

MURAI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV, FAC SCI, DEPT CHEM, SAPPORO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 09期

关键词：

D O I：

10.1246/cl.1994.1611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound with all the necessary functional groups of the KLM ring system in ciguatoxin, which is one of the most complicated toxic substances of marine origin, was synthesized stereoselectively. The crucial steps involve construction of the ethynyl alcohol, the delta-valerolactone, and the natural acetals.

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页码：1611 / 1614

页数：4

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