A NEW CATALYTIC TRANSFORMATION OF DIAZO ESTERS - HYDRIDE ABSTRACTION IN DIRHODIUM(II)-CATALYZED REACTIONS

被引：47

作者：

DOYLE, MP

DYATKIN, AB

AUTRY, CI

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 06期

关键词：

D O I：

10.1039/p19950000619

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary benzylic and allylic diazoacetates undergo dirhodium(II)-catalysed diazo decomposition to form, competitively or exclusively, ketone and vinylidene products from intramolecular hydride abstraction in catalyst ligand-dependent molar ratios.

引用

页码：619 / 621

页数：3

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