SELECTIVE RING-OPENING REACTION OF STYRENE OXIDE WITH LITHIUM AZIDE IN THE PRESENCE OF CYCLODEXTRINS IN AQUEOUS-MEDIA

被引：22

作者：

GUY, A

DOUSSOT, J

GARREAU, R

GODEFROYFALGUIERES, A

机构：

[1] Laboratoire de Chimie Organique (URA 1103) Conservatoire National des Arts et Métiers, 75141 Paris Cedex 03, 292, rue Saint-Martin

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)80202-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Regioselective ring-opening of racemic styrene oxide was achieved by lithium azide in the presence of beta-cyclodextrin in aqueous media. Kinetic resolution of racemic epoxide was observed and 1-phenyl-2-azido-ethanol was obtained with 78 % ee.

引用

页码：247 / 250

页数：4

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