RING-SIZE SPECIFIC TRANSFORMATIONS OF COBALT(III)-THIOETHER CHELATES ACTIVATED BY BASE - CO-C FORMATION OR C-S CLEAVAGE

被引：20

作者：

CHAKRABORTY, P ^{[1
]}

CHANDRA, SK ^{[1
]}

CHAKRAVORTY, A ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1021/om00036a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The A ring which is six-membered in 1 and five-membered in 2 is activated by alkali leading to the transformations 1 --> 3 (Co-C bond formation) and 2 --> 4 (C-S bond cleavage). This specificity has been rationalized in terms of a simple scheme which is extendable to other systems as well. The X-ray structure of the 1:1 chloroform adduct of complex 3 is reported.

引用

页码：4726 / 4727

页数：2

共 10 条

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