A POLYMERIC TELLURIUM CATION BY OXIDATION OF TELLURIUM WITH TUNGSTEN BROMIDES

被引：22

作者：

BECK, J

机构：

[1] Institut für Anorganische Chemie, Universität Engesserstrasse, Karlsruhe

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polymeric tellurium cation infinity 1[Te7(2+)] in Te7WOBr5 is made up of almost planar Te7 units, which are linked to form a folded band (see Figure). Related structural motifs were hitherto only known in the case of tellurium polyanions. Te7WOBr5 can be obtained by oxidation of tellurium with a WOBr4/WBr5 mixture.

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页码：1128 / 1130

页数：3

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