DECOMPOSITION OF DIOXIRANES INDUCED BY DIALKYL ETHERS

被引：25

作者：

FERRER, M ^{[1
]}

SANCHEZBAEZA, F ^{[1
]}

CASAS, J ^{[1
]}

MESSEGUER, A ^{[1
]}

机构：

[1] CSIC,CID,DEPT BIOL ORGAN CHEM,E-08034 BARCELONA,SPAIN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 18期

关键词：

ETHER; RADICALS; DIMETHYLDIOXIRANE; METHYL(TRIFLUOROMETHYL)DIOXIRANE;

D O I：

10.1016/S0040-4039(00)76677-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple dialkyl ethers (i.e, diethyl or dihexyl ether), in addition to undergo oxidative cleavage by reaction with methyl(trifluoromethyl)dioxirane or dimethyldioxirane, induce the decomposition of these oxidation reagents in a concentration dependent manner. The identification of compounds derived from reactions with species such as CH3. or CF(3)C0(2.) suggests that the above decomposition is a radical chain process.

引用

页码：2981 / 2984

页数：4

共 11 条

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